4.3 Article Proceedings Paper

Green photochemistry:: Production of fine chemicals with sunlight

Journal

PURE AND APPLIED CHEMISTRY
Volume 79, Issue 11, Pages 1939-1947

Publisher

WALTER DE GRUYTER GMBH
DOI: 10.1351/pac200779111939

Keywords

solar chemistry; photoacylation; photooxygenation; green chemistry; photochemistry

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Three photochemical reactions were investigated under solar irradiation conditions with moderately concentrated sunlight: the photoacylation of naphthoquinone with butyraldehyde and the dye-sensitized photooxygenations of citronellol and 1,5-dihydroxynaphthalene, respectively. All reactions were easily performed on multigram-to-kilogram scales using cheap and commercially available starting materials, and yielded important key intermediates for industrial applications.

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