Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2007, Issue 33, Pages 5483-5486Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200700648
Keywords
total synthesis; epoxidation; cyclotrimerisation; Wilkinson's catalyst
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Facile construction of benzene-fused 8-oxabicyclo[3.2.1]octane systems by employing a cross alkyne cyclotrimerisation reaction was explored. With this procedure, (-)-bruguierol A was synthesised, and its absolute configuration was established.
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