Journal
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN
Volume 76, Issue 11, Pages -Publisher
PHYSICAL SOC JAPAN
DOI: 10.1143/JPSJ.76.113602
Keywords
solvation effect; critical phenomena; small-angle neutron scattering
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Funding
- Grants-in-Aid for Scientific Research [18068012] Funding Source: KAKEN
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The effect of adding sodium tetraphenylborate (NaBPh4) on a LCST type phase separation of a mixture of D2O and 3-methylpyridine is investigated by visual observation and small-angle neutron scattering (SANS). In the case that the amount of salt is smaller than 50 mM, the mixture colors below the phase separation temperature. When the amount of salt is increased, the phase separation disappears and a single peak profile is observed at finite-Q by SANS. These results indicate that a periodic structure is induced in one phase region by the addition of NaBPh4.
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