Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 349, Issue 16, Pages 2493-2498Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200700319
Keywords
alkynes; alkynyloxiranes; cycloisomerization; epoxides; furans; gold
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An efficient approach to 2,5-disubstituted furans has been developed by utilizing gold-catalyzed sequential nucleophilic attack onto metal-complexed alkynes with complete regioselectivity. The reaction proceeds efficiently under mild conditions with commercially available catalysts to afford furans in moderate to excellent yields (up to 96 %) with high diversity.
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