4.7 Article

Self-catalyzed oxidation of sulfides with hydrogen peroxide: A green and practical process for the synthesis of sulfoxides

Journal

ADVANCED SYNTHESIS & CATALYSIS
Volume 349, Issue 16, Pages 2425-2430

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200700206

Keywords

green chemistry; selective oxidation; self-catalyzed; solvent free; sulfoxide

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A self-catalyzed selective oxidation of sulfides to sulfoxides has been developed. The scope of the protocol is demonstrated in the selective oxidation of 17 different substrates. High yields and chemoselectivity (in general > 90%) are achieved in most cases.

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