Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 129, Issue 44, Pages 13402-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja0763044
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Funding
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0848280] Funding Source: National Science Foundation
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The Ni(0)-catalyzed [2 + 2 + 2 + 2] cycloadditions of 1,6- and 1,7-diynes are shown to provide an efficient and selective method for the preparation of 1,2,5,6-tetrasubstituted cyclooctatetraenes; (COTs). Catalysts and conditions are described that favor in all cases COT formation over competing [2 + 2 + 2) cycloadditions. A hitherto unexplored crossed reaction is also described, providing access to non-symmetrical COTs.
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