Journal
ORGANIC LETTERS
Volume 9, Issue 23, Pages 4749-4751Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol7020737
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- NCI NIH HHS [CA 09112] Funding Source: Medline
- NIGMS NIH HHS [GM 58160, F32 GM 074407] Funding Source: Medline
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A copper-catalyzed method is described for the preparation of N-alkylbenzimidazoles in regioisomerically pure form starting from o-haloanilines. The method utilizing CuI and trans-N,N'-dimethyl-1,2-cyclohexanediamine allows the preparation of N-alkylbenzimidazoles in good to excellent yields.
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