4.8 Article

Acid-catalyzed rearrangement of fused alkylideneoxetanols

Journal

ORGANIC LETTERS
Volume 9, Issue 23, Pages 4681-4684

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol701625q

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Complex aza-fuzed tricyclic lactones are obtained in a two-step photochemical cycloaddition/acid-catalyzed rearrangement of simple alkoxy maleimide derivatives. The sequence involves a complex acid-catalyzed skeletal rearrangement of the intermediate alkylideneoxetanols.

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