Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 72, Issue 23, Pages 8947-8949Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo701668s
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[GRAPHICS] The first asymmetric total synthesis of spongotine A is described. The oxidative synthesis of the imidazoline/ketone unit from keto aldehyde and diamine is a key step in this synthesis. The absolute stereochemistry of the asymmetric center of natural spongotine A is revealed as the (S)configuration.
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