Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 72, Issue 23, Pages 8943-8946Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo7015983
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[GRAPHICS] An experimentally simple, efficient, and inexpensive catalyst system was developed for the N-arylation of pyrroles, indoles, and imidazole with aryl and heteroaryl iodides, bromides, and chlorides by applying CuI as catalyst, N-hydroxy-succinimide (L-1), N-hydroxymaleimide (L-2), or N-hydroxyphthalimide (L-3) as ligand, CH3ONa as base, and DMSO as solvent. A variety of functional groups are tolerated in the reaction, including those that are not compatible with Pd-catalyzed amidation methodology.
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