Journal
INORGANIC CHEMISTRY
Volume 46, Issue 23, Pages 9754-9759Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic701162j
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New luminescent isomeric europium(III) complexes with carboxylic carbonyl group coordination (I and II) have been prepared by solvothermal synthesis using the ligand 2,2 '-bipyridine-4,4 '-dicarboxylic acid (bpdc), with the nonradiatively shielded Eu3+ coordination sphere completed by dimethyl sulfoxide ligands. The room temperature IR spectra and Eu3+ luminescence spectra do not provide a definitive distinction between I and II, but low-temperature luminescence can give a clear identification.
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