Journal
INORGANIC CHEMISTRY
Volume 46, Issue 23, Pages 9519-9521Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic701371f
Keywords
-
Categories
Ask authors/readers for more resources
The crystal structures of two metallo oxides, perrhenate and dichromate, are reported with a diprotonated tetraamido/diaminobased macrocycle, L, in which the floppy ligand assumes a folded conformation. When the four amides are deprotonated, this same ligand binds transition-metal ions in its tetraanionic form, H-4L. For the divalent metal ions Cu2+ and Ni2+, H-4L again folds and dinuclear complexes are formed. With trivalent metal ions Co3+ and Fe3+, the ligand wraps about the metal ions, resulting in mononuclear complexes.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available