Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 692, Issue 24, Pages 5429-5439Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2007.09.002
Keywords
N-aryl-2-pyridylamines; preparation; Pd-II dimeric complexes; NMR; ESI-MS
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Palladium complexes of N-phenyl-2-pyridylamine (4) and dipyridylamine substrates (7, 11) have been studied. Due to the coordination ability of the pyridine-nitrogen atoms, the pyridyl substrates, 4, 7, 11 were subjected to Pd(OAc)(2) complexations and a number of N-aryl-2- pyridylamine Pd complexes (13-17) were isolated and characterised, in particular by NMR and ESI-MS. A new method for the preparation of the acetato-bridged six-membered ring palladacycle complex (13) of 4 is reported. The dipyridyl amines 7, 11 formed cis/trans bis-dentate acetato-bridged dimeric Pd(2)Lig(2)(OAc)(2) (14a,b/16a,b) and Pd(3)Lig(2)(OAc)(4) complexes (15a,b/17a,b). The N-aryl-2- pyridylamine substrates ( 4, 7, 11) were prepared by oxidative nucleophilic substitution, by 1,3-cycloaddition reaction or by Buchwald amination. (C) 2007 Elsevier B.V. All rights reserved.
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