Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 129, Issue 46, Pages 14138-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja075544g
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- NCRR NIH HHS [S10RR 020959] Funding Source: Medline
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Pulse electron-electron double resonance distance measurements between two high spin Gd3+ ions in a novel bis-Gd3+ complex involving two pyridine-based gadolinium tetracarboxylate systems linked by a rigid aryl-alkyne unit were carried out at Ka- and W-band frequencies. The experimental distance found was 2.02 +/- 0.02 nm, and it was further compared with the Gd3+-Gd3+ distance (2.2126 nm) determined by density functional theory.
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