Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 129, Issue 46, Pages 14120-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja075488j
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An efficient palladium(II)-catalyzed oxidative carbohydroxylation of allene-substituted conjugated dienes in aqueous media has been developed. The reaction is conducted employing p -benzoquinone as the stoichiometric reoxidant for the palladium or under aerobic conditions with essentially the same outcome. It is worth mentioning that this is the first example of a palladium(II)-catalyzed oxidation where a carbon-carbon bond is formed in water and also one of the few cases of nucleophilic attack by water on a (pi-allyl)palladium complex.
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