Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 129, Issue 46, Pages 14158-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja076346s
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Asymmetric 1,3-rearrangement of an alkynyl group of alkynyl alkenyl carbinols giving beta-alkynylketones took place in high yields with high enantioselectivity in the presence of a hydroxyrhodium/(R )-binap catalyst. The present method including a key beta-alkynyl elimination step in the catalytic cycle is synthetically equivalent to the asymmetric conjugate addition of terminal alkynes to beta-substituted enones.
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