Organic geochemistry and petrology of barren and Mo-Ni-PGE mineralized marine black shales of the Lower Cambrian Niutitang Formation (South China)

Marine black shales of the Lower Cambrian Niutitang Fort-nation in southern China host Mo-Ni-platinum group elements (PGE) mineralization confined to a phosphate- and pyrite-rich stratiform body (max. 20-cm thick). The H/C atomic ratio, carbon isotopic composition, FTIR spectra of bulk organic matter, and spectra of extractable part of organic matter indicate similar sources and thermal evolution of organic matter in barren and mineralized black shales. The morphology and relative abundance of organic particles in barren and mineralized shales are different. In barren black shales, organic particles comprise only elongated bodies and laminae 2-10 mu m across or elongated larger bodies (> 10 mu m) with R-max = 2.96-5.21% (Type 1 particles). Mineralized black shales contain Type I particles in rock matrix (90-95 vol%), small veinlets or irregular organic accumulations (Type 11 particles, 1-5 vol%) that display weak to well developed mosaic texture and a variable reflectance (R-max = 3.55-8.65%), and small (< 1 to 5 pm) rounded or irregular Type III organic particles (1-4 vol%) distributed within phosphate nodules and sulphide rip-up clasts. Type III particles show similar reflectance as particles of Type I in rock matrix. Type I particles are interpreted as remnants of in situ bacterially reworked organic matter of cyanobacteria/algal type, Type 11 as solidified products or oil-derived material (migrabitumen), and Type III particles as remnants of original organic matter in phosphatized or sulphidized algal/microbial oncolite-like bodies. Equivalent vitrinite reflectances of Type I and III particles in barren and mineralized rocks are similar and correspond to semi-anthracite and anthracite. Micro-Raman spectra of organic particles in rocks display a wide belt in the area of 1600 cm(-1) (G belt) and approximately the same belt in the area of 1350 cm(D belt). The ratio of integrated areas of the two belts correlate with R-max values. The Mo-Ni-PGE mineralized body is interpreted as to represent a remnant of phosphate- and sulphide-rich subaquatic hardground supplied with organic material derived from plankton and benthic communities as well as with algal/microbial oncolite-like bodies that originated in wave-agitated, shallow-water, nearshore environment. (c) 2007 Elsevier B.V. All rights reserved.