Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 72, Issue 24, Pages 9350-9352Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo7020357
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[Graphics] Functionalized chiral ionic liquids were found to be highly effective and reusable organocatalysts for asymmetric Michael additions of 4-substituted cyclohexanones. The desymmetrization reaction afforded the desired Michael adducts bearing three carbon stereocenters with up to 99% ee.
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