Journal
INORGANIC CHEMISTRY
Volume 46, Issue 24, Pages 10035-10037Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic701365t
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A criterion for the height of the anisotropy barrier Delta = vertical bar D vertical bar S-2 in single-molecule magnets, and therefore the blocking temperature T-B proportional to Delta, is presented. In particular, it is found that the anisotropy barrier does not increase with S as S-2 but as S-0. Consequences concerning the strategies to enhance Delta or T-B, respectively, are discussed.
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