Journal
INORGANIC CHEMISTRY
Volume 46, Issue 24, Pages 10168-10173Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic701236v
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The selective encapsulation behavior of cucurbit [5]uril and its lanthanide-capped molecular capsule toward nitrate and chloride ions has been investigated. Using fluorescence spectroscopy, the metal-free host has been demonstrated to selectively include nitrate ion. In contrast, the lanthanicle-capped molecular capsule showed preference toward the inclusion of chloride ion. Solid-state structures of the nitrate and chloride inclusion complexes with the La(III)-capped molecular capsule have been crystallographically determined.
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