Journal
TETRAHEDRON LETTERS
Volume 48, Issue 48, Pages 8460-8463Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2007.09.159
Keywords
carbon-carbon bond forming reaction; supercritical fluid; hydroxyalkylation; acetonylation; uncatalyzed reaction
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The reactions of the alkenes with supercritical organic compounds under non-catalytic conditions were investigated. The H and CR2OH, CH2C = OCH3 or CH2C N of supercritical alcohols (CHR2OH), acetone (CH3C = OCH3) or acetonitrile (CH3C N) added to the C = C bonds of alkenes form C-C bonds between the alpha-carbons of the supercritical organic compounds and the sp(2) carbons of the alkenes. (c) 2007 Elsevier Ltd. All rights reserved.
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