Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 349, Issue 17-18, Pages 2641-2646Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200700372
Keywords
allylic substitution; pi-allyl-iron complexes; amine-iron carbonyl complexes; diiron nonacarbonyl; homogeneous catalysis
Categories
Ask authors/readers for more resources
The combination of diiron nonacarbonyl and dimethylamine gives an active catalyst for displacement of allylic acetate by diethyl methylmalonate. It was found that among a series of amines, only dimethylamine and morpholine were efficient promoters of the reaction. Solvents such as dimethylformamide (DMF) and N-methylformamide were much superior to tetrahydrofuran, dichloromethane, and ethanol.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available