4.1 Article

Equations of state of MgO, au, pt, NaCl-B1, and NaCl-B2: Internally consistent high-temperature pressure scales

Journal

HIGH PRESSURE RESEARCH
Volume 27, Issue 4, Pages 431-446

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1080/08957950701659700

Keywords

expanded Mie-Gruneisen-Debye EoS; pressure scales; Gruneisen parameter; intrinsic anharmonicity; gold; platinum; magnesium oxide; sodium chloride

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Semiempirical equations of state (EoS) of An, Pt, MgO, NaCl-B1, and NaCl-B2 based on expanded Mie-Gruneisen-Debye approach, which are consistent both with the Mie-Gruneisen-Bose-Einstein approach and the thermochemical, X-ray, ultrasonic and shock-wave data in a wide pressure-temperature range, have been constructed. It is shown that to determine the volume dependence of the Gruneisen parameter, not only shock-wave and static compression data, but also experimental information on heat capacity, bulk moduli, volume, and thermal expansion coefficient at zero pressure need to be taken into account. Intrinsic anharmonicity is of great importance at construction of EoS at high temperatures and x = V/V-0 > 1. Cross-comparison of the current equations of state with independent measurements shows that these EoS may be used as the internally consistent and independent pressure scales in a wide range of temperatures and pressures.

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