Adsorptive stripping voltammetric determination of ultra trace of zinc and lead with carbidopa as complexing agent in food and water samples

In the present work, the cathodic stripping voltammetric methodology using a hanging mercury drop electrode was described for simultaneous determination of lead and zinc in different real samples. ne method is based on adsorption of metal ions on mercury electrode using carbidopa as a suitable complexing agent. The potential was scanned to the negative direction and the differential pulse stripping voltammograms were recorded. Optimal conditions were found to be: accumulation time; 70 s, accumulation potential; 50 mV versus Ag/AgCl, scan rate; 40 mV s(-1), supporting electrolyte; 0.01 M ammonia buffer at pH 8.5, and concentration of carbidopa; 8.0 mu M. The relationship between the peak current versus concentration was linear over the range of 0.1-210 and 0.2-170 nM for lead and zinc, respectively. The detection limits are 0.09 and 0.15 nM for lead and zinc ions respectively. The relative standard deviations at a concentration level of 70 nM of both metal ions are found 1.08 and 1.24% for lead and zinc ions respectively.