3.8 Article

11B nuclear magnetic resonance study on existence of boron-hydrogen complex in boron-doped diamond

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Publisher

INST PURE APPLIED PHYSICS
DOI: 10.1143/JJAP.46.L1138

Keywords

boron-doped diamond; B-11 NMR; two-dimensional NMR

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The assignment of boron not contributing to conductivity in boron-doped diamond to boron-hydrogen complex is reexamined using a new B-11 two-dimensional NMR technique, which is developed to detect H-1-B-11 dipolar broadening. It is shown that the amount of boron-hydrogen complex is not substantial and the previous assignment is thus less plausible. Possible mechanisms of linebroadening are discussed.

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