Journal
ACCOUNTS OF CHEMICAL RESEARCH
Volume 40, Issue 12, Pages 1327-1339Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ar7001864
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Within the realm of catalytic asymmetric hydrogenation, the focus continues to be on the use of chiral metal complexes in conjunction with a hydrogen Source. Recently, the widespread development of organocatalysis, including the invention of iminium activation, has led to the discovery of many new enantioselective transformations. Based on this strategy, a number of bioinspired processes for the enantioselective organocatalytic transfer hydrogenation of alpha,beta-unsaturated carbonyl Compounds and imines have been discovered. These topics will be the focus of this Account.
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