Oxidation of the Polycrystalline Gold Foil Surface and XPS Study of Oxygen States in Oxide Layers

Gold oxide films obtained on the surface of polycrystalline gold foil upon oxidation by oxygen activated by a high-frequency discharge have been studied by X-ray photoelectron spectroscopy. High-frequency O-2 activation affords oxide films more than 3-5 mu thick. As follows from Au4f spectra, the surface gold atoms are oxidized to the oxidation state +3. The Ols spectra have a composite shape and are decomposed into four components that characterize nonequivalent states of oxygen in the resulting oxide films. It is assumed that the two major oxygen states (E-b (O1s) = 529.0 and 530.0 eV) correspond to the oxygen atoms in two- and threedimensional gold oxide Au2O3, respectively. The oxygen states characterized by the higher binding energies (E-b (O1s) = 531.8 and 535.2 eV) likely correspond to molecular oxygen in peroxide and superoxide groups, respectively.