4.2 Article

Synthesis of aryl(hetero)methylene-1,3-indandione based molecular glasses

Journal

MONATSHEFTE FUR CHEMIE
Volume 138, Issue 12, Pages 1243-1248

Publisher

SPRINGER WIEN
DOI: 10.1007/s00706-007-0748-5

Keywords

1,3-indandione; 1,2,3,4-tetrahydroquinoline; molecular glasses; ionization potential; charge mobility

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Novel glass-forming 2-(1-phenyl-1,2,3,4-tetrahydroquinoline-6-ylmethylene)-1,3-indandione derivatives were synthesized and their thermal properties were studied. The results of a preliminary investigation of the photoelectric properties of amorphous films of the title compounds are briefly reported. The ionization potential of these molecular glasses is ca. 5.6eV and the hole drift mobility exceeds 10(-8)cm(2)V(-1)s(-1) at strong electric fields.

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