Journal
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
Volume 59, Issue 3-4, Pages 287-292Publisher
SPRINGER
DOI: 10.1007/s10847-007-9325-0
Keywords
gossypol; inclusion compound; iodine; organic zeolite; polymorph; sorption
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Gossypol has been obtained in the zeolite-like form by desolvation of the 1:1 unstable solvate with dichloromethane. It demonstrates a high potential for an uptake of molecular iodine from the environment. In a case of single crystals a stable inclusion compound (gossypol)(8)center dot I-2, preserving the crystal structure of the zeolite-like form, has been prepared. The iodine molecules occupy large cavities of the channels and are inclined as confirmed by the absence of a strong dichroism. The iodine molecules can be removed with the help of vacuum giving back to the zeolite-like form.
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