4.5 Article

Thermodynamic assessment of the Bi-Sn-Zn system

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PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.calphad.2007.05.002

Keywords

lead-free solders; Bi-Sn assessment; Bi-Sn-Zn assessment; CALPHAD approach; COST531 database

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A thermodynamic assessment of the Bi-Sn-Zn ternary system was carried out using the CALPHAD approach along with thermodynamic descriptions from new assessments of the Bi-Sn and Bi-Zn systems. Selected experimental data from the literature and our own work were also used. New sets of optimized thermodynamic parameters were obtained that lead to a very good fit between the calculated and experimental data. The Bi-Sn-Zn system is one of the candidates for lead-free solder materials. (c) 2007 Elsevier Ltd. All rights reserved.

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