4.6 Article

Electrooxidation of 2-propanol on Pt, Pd and Au in alkaline medium

Journal

ELECTROCHEMISTRY COMMUNICATIONS
Volume 9, Issue 12, Pages 2760-2763

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2007.09.016

Keywords

fuel cells; 2-propanol electrooxidation; palladium; gold; alkaline medium

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Pd and Au are investigated as electrocatalysts for 2-propanol oxidation and compared with the conventional catalyst of Pt in alkaline medium. The current density for 2-propanol oxidation on Pd electrode is much higher than that on Pt electrode. The onset potential for 2-propanol oxidation on Pd electrode is more negative compared with that on Pt electrode. The results show that Pd is a good electrocatalyst for 2-propanol oxidation and the activity for the electrooxidation of 2-propanol is higher than Pt and Au in alkaline medium. Pd has higher electrocatalytic activity and better stability for the electrooxidation of 2-propanol. The present study shows a promising choice of Pd as effective electrocatalyst for 2-propanol electrooxidation in alkaline medium. (C) 2007 Elsevier B.V. All rights reserved.

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