Journal
ADVANCED MATERIALS
Volume 19, Issue 23, Pages 4279-+Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200701228
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The effect of template phase on the structures of as-synthesized silica nanoparticles with fragile DDAB vesicles as templates is reported. It is found that the template phase plays a critical role in the growth process of silica: the unstable DDAB vesicles in liquid-crystalline phase often lead to the formation of mesostructured solid spheres, and the rather stable DDAB vesicles in gel phase lead to the formation of hollow spheres with less mesostructures.
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