Journal
SYNLETT
Volume -, Issue 19, Pages 3027-3031Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2007-990965
Keywords
triazine; retro-Diels-Alder; gallate; fluorescence; platinum
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A simple protocol for the efficient preparation of substituted 6-phenyl-2,2'-bipyridine derivatives is described. A reverse type of Diels-Alder reaction between a 6-phenyl-2-pyridyl-1,3,4-triazine and 4-N,N-di-n-butylaminophenyl- or gallate-ethynyl derivatives at high temperature provide a mixture of two products easily separable by column chromatography. A variety of ligands suitable for the synthesis of cyclometalated platinum complexes have been produced. Additional substitution of the Pt-Cl by various donor-acceptor ethynyl fragments is feasible by mean of copper(I) catalysis.
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