Journal
ORGANIC LETTERS
Volume 9, Issue 25, Pages 5319-5321Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol702557s
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The construction of a new type of bicyclo[4.4.0]decene products with a conjugated exocyclic diene unit was developed using Rh-catalyzed cyclization of 1,5-bisallenes in the presence of monoallenes. The steroid-like tetracyclic products could be obtained by applying an alkylation-Diels-Alder process.
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