Journal
JOURNAL OF POWER SOURCES
Volume 174, Issue 2, Pages 1117-1120Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2007.06.099
Keywords
cyclic voltammetry; aqueous LiNO3 solution; cathodic materials; LiCr0.15Mn1.85O4; LiMn2O4; glycine-nitrate method
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Cyclic voltammetry (CV) of LiCr0.15Mn1.85O4, synthesized by rapid glycine-nitrate method (GNM), was performed in a saturated aqueous LiNO3 (similar to 9 M) solution. At rather high polarization rate of 10 mV s(-1) two well separated characteristic pairs of redox peaks can be clearly observed, which is not entirely the case for LiMn2O4 synthesized in the same way. At a reduced scan rate of 1 mV s(-1), the shape and position of redox peaks evidence that deintercalation/intercalation of Li+ ion is highly reversible and much faster than in the case of organic electrolytes. Faster CV response of LiCr0.15Mn1.85O4 is in correlation with higher capacity retention (93%) in comparison to LiMn2O4 (88%), registered after 50 charging/discharging cycles in organic electrolyte solution (1 M LiClO4 in propylene carbonate). (c) 2007 Elsevier B.V. All rights reserved.
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