4.4 Article

Novel quinone-fused corroles

Journal

TETRAHEDRON LETTERS
Volume 48, Issue 50, Pages 8904-8908

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2007.10.054

Keywords

corroles; 1,3-dipolar cycloadditions; azomethine ylides; quinones

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Gallium(III)(pyridine) complex of 5,10,15-tris(pentafluorophenyl) corrole-3-carbaldehyde was used as a precursor of an azomethine ylide, which was trapped in 1,3-dipolar cycloaddition reactions with quinones. Besides the expected dehydrogenated 1,3-dipolar cycloadducts, novel quinone-fused corrole derivatives were also obtained in moderate yields. (c) 2007 Elsevier Ltd. All rights reserved.

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