Athermal resistance to interface motion in the phase-field theory of microstructure evolution

A method of introducing an athermal resistance to interface propagation for the Ginzburg-Landau (GL) approach to the first-order phase transformations (PTs) is developed. It consists of introducing oscillating fields of stresses (due to various defects or a Peierls barrier) or a jump in chemical energy. It removes some essential drawbacks in GL modeling: it arrests experimentally observed microstructures that otherwise converge to a single phase, and it reproduces rate-independent stress hysteresis. A similar approach can be applied for twinning, dislocations, and other PTs (e.g., electric and magnetic).