Journal
JOURNAL OF NON-CRYSTALLINE SOLIDS
Volume 353, Issue 52-54, Pages 4762-4766Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jnoncrysol.2007.06.057
Keywords
FTIR measurements; infrared properties; oxide glasses; germania; structural relaxation; water in glass
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A simple IR method of determining the fictive temperature of GeO2 glass, both surface and bulk, was developed using the same technique developed earlier for silica glass. Specifically, IR absorption and reflection peak wavenumbers of GeO2 structural bands were found to be correlated with the fictive temperature of the glass. Using this method structural relaxation kinetics can be investigated. Density and refractive index of GeO2 glass were also measured as a function of fictive temperature. (c) 2007 Published by Elsevier B.V.
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