Journal
ADVANCED MATERIALS
Volume 19, Issue 24, Pages 4552-+Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200701866
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A new crosslinking system based on azide-functionalized random copolymers has been defined for the preparation of substrates with controllable surface interactions. The azido group is used for both thermal- and photo-crosslinking, which is found to be very efficient. Furthermore, the use of UV irradiation for crosslinking enables the preparation of patterned surfaces by conventional photolithographic techniques, combining the bottom-up self-assembly of block copolymer strategies with traditional top-down photolithographic methods.
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