Journal
JOURNAL OF PHYSICAL CHEMISTRY A
Volume 111, Issue 50, Pages 12972-12976Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp077278z
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The perchlorate complexes of manganese, nickel, and zinc with hexamethylenetetramine (HMTA) of the general formula [M(H2O-HMTA-H2O)(2)(H2O-ClO4)(2)(H2O)(2)] (where M = Mn, Ni, and Zn) have been prepared and characterized by X-ray crystallography. Thermal studies were undertaken using thermogravimetry (TG), differential thermal analysis (DTA), and explosion delay (DE) measurements. The kinetics of thermal decomposition of these complexes was investigated using isothermal TG data by applying isoconversional method. The decomposition pathways of the complexes have also been proposed. These were found to explode when subjected to higher temperatures.
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