Journal
ORGANIC LETTERS
Volume 9, Issue 26, Pages 5577-5580Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol702548r
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The reaction of alkyl-substituted sec-ethoxyalkynyl acetates with water catalyzed by Hg(OTf)(2) afforded alpha,beta-unsaturated esters in excellent yield with high catalytic turnover up to 1000 times under very mild reaction conditions with virtually complete E-selectivity, superior even to that of the HWE reaction.
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