Journal
ORGANIC LETTERS
Volume 9, Issue 26, Pages 5601-5604Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol702456z
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simple yet powerful Ni catalyst can be used to promote direct arylations of alpha-halocarbonyl compounds, including a range of esters, amides, and ketones, with various arylboronic acids under mild conditions. The method tolerates beta-hydrogens and functional groups in the substrates and offers reactivity and selectivity profiles that are complementary to those found in the well-established Buchwald-Hartwig approach.
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