Journal
PHYSICAL REVIEW LETTERS
Volume 99, Issue 25, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.99.256402
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The temperature dependence of charge order in Fe2OBO3 was investigated by resistivity and differential scanning calorimetry measurements, Mossbauer spectroscopy, and synchrotron x-ray scattering, revealing an intermediate phase between room temperature and 340 K, characterized by coexisting mobile and immobile carriers, and by incommensurate superstructure modulations with temperature-dependent propagation vector (1/2, 0, tau) . The incommensurate modulations arise from specific antiphase boundaries with low energy cost due to geometrical charge frustration.
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