Journal
JOURNAL OF PHYSICAL CHEMISTRY A
Volume 111, Issue 51, Pages 13623-13628Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp0756348
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Applying a modified high accuracy extrapolated ab initio thermochemistry (HEAT) scheme, the standard heat of formation of vinyl chloride at 0 K is computed to be 29.79 +/- 1 kJ/mol and at 298.15 K to be 20.9 +/- 2 kJ/mol, thus resolving earlier discrepancies among the available experimental values, which span a range from 21 up to 38 kJ/mol. The enthalpies of the reactions C2H4 + Cl-2 -> CH2CHCl + HCl and C2H2 + HCl -> CH2CHCl at 298.15 K are determined to be - 123.0 and - 113.9 +/- 2 kJ/mol, respectively.
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