Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 40, Issue 33, Pages 10439-10452Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2015.06.084
Keywords
Steam reforming; Cu-MCM-41; Metal loading; One-pot synthesis; Catalyst deactivation; N2O chemisorption
Categories
Funding
- National Science Foundation (NSF) for the NSF-CREST Bioenergy Center [HRD-124215]
- Division Of Human Resource Development
- Direct For Education and Human Resources [1242152] Funding Source: National Science Foundation
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High surface area MCM-41 containing copper catalysts (with different loading from 5 to 20 wt%) were synthesized using one-pot procedure for steam reforming of methanol (SRM) studies. A variety of techniques including BET, XRD, TGA-DSC, TEM, EDX, ICP-OES, H-2-TPR, N2O chemisorption and EPR were used to characterize the physical and chemical properties of catalysts. Structural characterization by means of XRD and BET revealed that %Cu loading has a strong influence on the ordered structure and the textural properties of the Cu-MCM-41 catalysts. The BET surface area of MCM-41 decreased from 1039 to 662 m(2)/g with increase in Cu loading from 0 to 15 wt% and then dropped to 314 m(2)/g with the loss of ordered structure at 20 wt% loading. The chemical composition analyses of catalysts using ICP-OES and EDX showed that the intended amount of copper was successfully retained in MCM-41 during one pot synthesis. Steam reforming of methanol for hydrogen production was carried out in a fixed bed reactor at atmospheric pressure in the temperature range of 200-350 degrees C. The effect of %Cu loading, reaction temperature, CH3OH/H2O molar ratio, reactants space velocity, catalyst time on-stream on the catalytic activity and selectivity were investigated. The Cu-MCM-41 samples showed excellent catalytic performance for the SRM reactions. The best results were obtained with 15%Cu-MCM-41 which showed similar to 89% methanol conversion, 100% H-2 selectivity and CO selectivity of 0.8% at 300 degrees C and 2838 h(-1) GHSV. However, methanol conversion decreased to about 77% when the loading of Cu was increased to 20 wt%. This can be attributed to more than 50% decrease in catalyst surface area leading to decrease in Cu-dispersion. The catalyst with 15 wt% loading showed strong resistance to deactivation and maintained consistent performance over a time on-stream for 48 h, indicating that the use of high surface area MCM-41 support significantly enhanced the stability of Cu-based catalyst. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
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