4.7 Article Proceedings Paper

Sonochemical synthesis of hollow Pt alloy nanostructures on carbon nanotubes with enhanced electrocatalytic activity for methanol oxidation reaction

Journal

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 40, Issue 41, Pages 14416-14420

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2015.03.142

Keywords

Electrocatalyst; Methanol oxidation reaction; Nanostructured composite materials; Fuel cells

Funding

  1. Shanghai Municipal Education Commission [12ZZ067]
  2. Shanghai Pujiang Program [11PJ400200]
  3. Fundamental Research Funds for the Central Universities [EG2015020]

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Hollow CoNiPt ternary alloy nanostructures loaded on carboxylated multiwalled carbon nanotubes (c-MWCNTs) are facilely synthesized under a sonochemical condition. The as-prepared CoNiPt/c-MWCNTs hybrid exhibits enhanced electrocatalytic activity and improved stability for methanol oxidation reaction (MOR), much superior to the corresponding pure Pt, binary CoPt and NiPt counterparts. The green sonochemical synthesis of CoNiPt/c-MWCNTs composite provides a promising strategy for developing of high-performance Pt-based catalysts for the MOR in fuel cells. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

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