Journal
PHYSICAL REVIEW A
Volume 79, Issue 1, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevA.79.012710
Keywords
ab initio calculations; carbon; charge exchange; ion-molecule collisions; positive ions
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The charge transfer in the collision of C4+ ions on 5-halouracil molecules has been studied theoretically by means of ab initio quantum chemistry molecular methods followed by a semiclassical dynamical treatment. The process appears markedly less efficient than the corresponding charge transfer with a uracil target which induces an enhancement of the complementary fragmentation process in agreement with the radio sensitivity of 5-halouracil molecules widely recognized. The mechanism seems to be driven by both electronic and steric effects which induce a lowering of the charge transfer cross sections and favor various orientations of the projectile with respect to the 5-halouracil target considered.
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