Journal
ATMOSPHERIC CHEMISTRY AND PHYSICS
Volume 9, Issue 21, Pages 8351-8363Publisher
COPERNICUS GESELLSCHAFT MBH
DOI: 10.5194/acp-9-8351-2009
Keywords
-
Funding
- NOAA Climate and Global Change Fellowship Program
- Div Atmospheric & Geospace Sciences
- Directorate For Geosciences [0846183] Funding Source: National Science Foundation
Ask authors/readers for more resources
The heterogeneous reaction of N2O5 on mixed organic-inorganic aerosol particles was investigated using an entrained aerosol flow tube coupled to a custom-built chemical ionization mass spectrometer. Laboratory results on aqueous particles confirm a strong dependence of the reactive uptake coefficient (gamma) on particle liquid water, for particle water concentrations below 15 M, and the molar ratio of particle water to nitrate. Measurements of gamma(N2O5) on mixed chloride-nitrate particles indicate that the presence of trace chloride can negate the suppression of gamma(N2O5) at high nitrate loadings with implications for polluted coastal regions. These results are used to construct a new parameterization for gamma(N2O5), that when coupled to an aerosol thermodynamics model, can be used within regional and/or global chemical transport models.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available