Journal
JOURNAL OF CHEMICAL SCIENCES
Volume 121, Issue 4, Pages 387-395Publisher
INDIAN ACAD SCIENCES
DOI: 10.1007/s12039-009-0045-4
Keywords
2-(Naphthyl-1 '-azo)-4-methylphenol; iridium; C-H activation; structure; electrochemical properties
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Funding
- Department of Science and Technology [SR/SI/IC-15/20041]
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Reaction of 2-(naphthyl-1'-azo)-4-methylphenol with [Ir(PPh3)(3)Cl] in refluxing ethanol in the presence of a base (NEW affords an organoiridium complex of type [Ir(PPh3)(2)(L)(H)], where L represents the coordinated 2-(naphthyl-1'-azo)-4-methylphenolate ligand. A similar reaction carried out in toluene affords the [Ir(PPh3)(2)(L)(H)] complex along with a similar complex of type [Ir(PPh3)(2)(L)Cl]. Structures of both the [Ir(PPh3)(2)(L)(H)] and [Ir(PPh3)(2)(L)Cl] complexes have been determined by X-ray crystallography. In both the complexes, 2-(naphthyl-1'-azo)-4-methylphenol is coordinated to iridium, via C-H activation at the 2' position of the naphthyl ring, as a dianionic tridentate C, N, O-donor and the two triphenylphosphines are trans. The organoiridium complexes show intense MLCT transitions in the visible region. Cyclic voltammetry on the [Ir(PPh3)(2)(L)(H)] and [Ir(PPh3)(2)(L)Cl] complexes shows a reversible Ir(III)-Ir(IV) oxidation respectively at 0.55 and 0.73 V vs SCE. An irreversible oxidation of the coordinated 2-(naphthyl-1'-azo)-4-methylphenolate ligand is observed above -1.0 V vs SCE and an irreversible reduction of the same is observed near -1.0 V vs SCE.
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