4.6 Article

Stability and instability in isothermal CFSTRs with complex chemistry: Some recent results

Journal

AICHE JOURNAL
Volume 59, Issue 9, Pages 3403-3411

Publisher

WILEY-BLACKWELL
DOI: 10.1002/aic.14110

Keywords

bistability; chemical reaction network theory; mathematical modeling; multistability; reactor analysis

Funding

  1. NSF [EF-1038394]
  2. NIH [1R01GM086881-01]
  3. Emerging Frontiers
  4. Direct For Biological Sciences [1038394] Funding Source: National Science Foundation

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Although the classical 1955 paper by Bilous and Amundson was largely devoted to the study of nonisothermal systems, they also found it worthwhile to establish the stable behavior of a model isothermal multireaction continuous flow stirred tank reactor for all values of residence time, rate constants, and feed concentrations. Over a half century later, there remains a predisposition to the idea that isothermal reactors are prone to dull, stable behavior even when the underlying chemistry is complex. That idea is revisited in light of some recent findings in chemical reaction network theory. (c) 2013 American Institute of Chemical Engineers AIChE J, 59: 3403-3411, 2013

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